Some Order information can be exported from the system to a CSV file. On the Orders page, you would define a search for orders using the available fields. Next to the Search button in the middle is the Export Search to CSV button. That will export any orders in your search to a CSV.
Only so much information is available in the export. This is how it will look in the CSV.
From the Ready to Ship Status, you also have a Export Shipping Information option. You can select orders, and hit that button to create a CSV of the Shipping Addresses. You can select UPS, Fedex or All shipping method, then click the 'Export' button. This will be all the information necessary to create shipping labels through any shipping service software.